HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bis(pinacolato)diborane → HCID 67447234, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reactant | tert-butyl N-[(4-bromophenyl)methyl]carbamate | HCID 12453839 | — |
| Reactant | 9-bromo-8-methoxythieno[2,3-c]quinolin-4(5H)-one | HCID 67449139 | — |
| Product | HCID 67447234 | HCID 67447234 | 68.7% |
Reaction Steps
Following General Procedure E, tert-butyl 4-bromobenzylcarbamate (2.9 g, 10 mmol) was reacted with bis(pinacolato)diborane (2.8 g, 11 mmol) to afford the crude boronic ester which was reacted with 9-bromo-8-methoxythieno[2,3-c]quinolin-4(5H)-one (2.8 g, 9.0 mmol) to afford the desired product (2.7 g, 68%) as a brown solid: ESI MS m/z 437 [C24H24N2O4S+H]+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08962648B2 |
| Source dataset | uspto-grants-2015_02 |
| ORD ID | ord-038c5ff2c8814fd38cf302eb414c0ffd |
| Source note | uspto-grants-2015_02 |