1-Butanol → HCID 23419109, compound

HRID 1855699Notes

Reaction equation

HRID 1855699 reaction equation
[N:1]1[P:6](Cl)(Cl)=[N:5][P:4](Cl)(Cl)=[N:3][P:2]=1(Cl)Cl.[CH2:13]([OH:17])[CH2:14][CH2:15][CH3:16]>N1C=CC=CC=1>[CH2:13]([O:17][P:2]1([O:17][CH2:13][CH2:14][CH2:15][CH3:16])[N:3]=[P:4]([O:17][CH2:13][CH2:14][CH2:15][CH3:16])([O:17][CH2:13][CH2:14][CH2:15][CH3:16])[N:5]=[P:6]([O:17][CH2:13][CH2:14][CH2:15][CH3:16])([O:17][CH2:13][CH2:14][CH2:15][CH3:16])[N:1]=1)[CH2:14][CH2:15][CH3:16]

Participants

4

Reactant 2

HCID 2631-ButanolHCID 220225Hexachlorocyclotriphosphazene

Product 1

HCID 23419109HCID 23419109, compoundYield 90%

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

To a chilled solution (0°-5° C.) of triphosphonitrilic chloride (0.018 mole) in 26 ml of pyridine, butanol (0.34 mole) was added. The mixture was stirred at room temperature overnight, diluted with petroleum ether and washed with dilute HCl, NaHCO3, and water successively. After removal of solvent, the product IIa was obtained in a yield of 90%. Found (and calcd. for C24H54N3O6P3 /M.W. 574): C 48.96 (50.25); H 9.29 (9.49); N 7.71 (7.33) and P 16.11 (16.23).

Workup

  1. washwashed with dilute HCl, NaHCO3, and water successively
  2. customAfter removal of solvent
  3. customthe product IIa was obtained in a yield of 90%

Sources & evidence

ORD record
ord-5666b6c598194e54af0dae93cf8c89c7
Source dataset
uspto-grants-1980_08
Patent number
US04216137

Reaction notes

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