4-Acetylbiphenyl → 4-(p-Phenyl-phenyl)-2-pentanone

HRID 1855787Notes

Reaction equation

[C:1]([C:4]1[CH:9]=[CH:8][C:7]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[CH:6][CH:5]=1)(=O)[CH3:2].[CH2:16]([OH:18])[CH3:17].[CH3:19]CCCC>>[C:10]1([C:7]2[CH:8]=[CH:9][C:4]([CH:1]([CH3:19])[CH2:2][C:16](=[O:18])[CH3:17])=[CH:5][CH:6]=2)[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

Participants

Reactant 2

HCID 71134-Acetylbiphenyl

HCID 19891530Ethanol pentane

Product 1

HCID 204960454-(p-Phenyl-phenyl)-2-pentanone

Procedure

As Example 14 using 4-acetyl biphenyl as the starting material. 4-(p-phenyl-phenyl)-2-pentanone was obtained as a colourless solid, m.p. 67° C. from ethanol/pentane.

Sources & evidence

ORD record: ord-bff902f11c0342cd97f919e072da54d5
Source dataset: uspto-grants-1980_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04216232

Reaction notes

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