HCID 86737135, compound → HCID 86737131, compound

HRID 1855801Notes

Reaction equation

HRID 1855801 reaction equation
[CH3:1]/[C:2](/[CH:7]=[CH:8]/[CH:9]=[C:10](\[CH3:21])/[CH:11]=[CH:12]/[C:13]1[C:17]([CH3:18])=[C:16]([CH3:19])[O:15][C:14]=1[CH3:20])=[CH:3]\[C:4]([O-:6])=[O:5].[K+].[CH3:23]/[C:24](/C=C/C=C(\C)/C=C/C1C(C)=C(C)OC=1C)=C\C([O-])=O.[Na+]>>[CH2:23]([O:5][C:4](=[O:6])/[CH:3]=[C:2](\[CH3:1])/[CH:7]=[CH:8]/[CH:9]=[C:10](\[CH3:21])/[CH:11]=[CH:12]/[C:13]1[C:17]([CH3:18])=[C:16]([CH3:19])[O:15][C:14]=1[CH3:20])[CH3:24]

Participants

3

Reactant 2

HCID 86737135HCID 86737135, compoundHCID 86737136HCID 86737136, compound

Product 1

HCID 86737131HCID 86737131, compound

Procedure

In a manner similar to that described in Example 11 potassium (E,E,E,E)-3,7-dimethyl-9-(2,4,5-trimethyl-3-furyl)-2,4,6,8-nonatetraenoate m.p. 200°-250° decomposition and sodium (E,E,E,E)-3,7-dimethyl-9-(2,4,5-trimethyl-3-furyl)-2,4,6,8-nonatetraenoate m.p. 210°-260° with decomposition were formed from (E,E,E,E)-3,7-dimethyl-9-(2,4,5-trimethyl-3-furyl)-2,4,6,8-nonatetraenoic acid ethyl ester.

Sources & evidence

ORD record
ord-54a8c870c1f0497a97f40aff67991306
Source dataset
uspto-grants-1980_08
Patent number
US04216312

Reaction notes

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