2-Chloroethanol → HCID 86644525, compound

Participants

Reaction Steps

To each of the glass ampoules (A), (B), (C), (D), (E), (F), (G), and (H), which had been thoroughly dried and flushed with nitrogen to replace the air, was added 1 ml of methyl oleate. To the ampoules (A), (B), (C), (D), and (E) was added each 0.05 millimole of (A) tetrachloroethylene, (B) ethylene chlorohydrin, (C) trichloroacetic acid, (D) p-chlorophenol, and (E) dinitrophenol, respectively. To the ampoules (F) and (G) were added 1 ml of oxygen and 0.2 millimole of p-chlorophenol, respectively. To every ampoule was added 2 ml of toluene solution of WCl6 (0.05 mole/liter) and, after 5 minutes of stirring, 0.6 ml of toluene solution of (C2H5)2AlCl (0.5 mole/liter). Reaction was carried out at 28° C. for 17 hours. From the ampoules (A)-(H), there was obtained [II] in yields of (A) 12%, (B) 11%, (C) 13%, (D) 16%, (E) 13%, (F) 7%, (G) 11%, and (H) 5%, respectively.

Provenance & Evidence