Diethyl Ether → HCID 23345671, compound

Participants

Reaction Conditions

Reaction Steps

To a solution of ethyl N-trifluoroacetyl-N-(dichlorophosphonomethyl)glycinate (6.6 g, 0.02 mole) in ether (200 ml.) was added a solution of allyl alcohol (2.32 g, 0.04 mole) and triethylamine (4.04 g, 0.04 mole) in ether (75 ml.). The resulting mixture was stirred for 3 days at 20° C. The mixture was filtered and the filtrate was concentrated in vacuo to afford a clear oil. This oil was extracted into petroleum ether, then concentrated in vacuo to give 6.25 g of ethyl N-trifluoroacetyl-N-(diallyloxyphosphonomethyl)glycinate as an oil, ND26.6 =1.4382.

Provenance & Evidence