HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Hydroxide → UV-328
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 4-Methyl-2-[2-(2-nitrophenyl)diazenyl]phenol | HCID 74029 | — |
| Reactant | 2-Nitro-2'-hydroxy-3',5'-bis(tert-amyl)azobenzene | HCID 104111 | — |
| Reactant | Sorbitan mono-(9Z)-9-octadecenoate | HCID 9920342 | — |
| Reactant | Span #80 (Sorbitan monooleate) | HCID 70693544 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Product | UV-328 | HCID 33263 | 71.9% |
Reaction Steps
When using the general procedure of Example 5, the 2-nitro-2'-hydroxy-5'-methylazobenzene was replaced by an equivalent amount of 2-nitro-2'-hydroxy-3',5'-di-tert-amylazobenzene and the sodium hydroxide was replaced by an equivalent amount of potassium hydroxide, the hydrogenation was run in an Amsco mineral spirits/water (40/60) medium containing 1% sorbitan monooleate, Span 80, wetting agent at a hydrogen pressure of 6 atmospheres for a total period of 8 hours. The above named product was obtained in an isolated yield of 71.9%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04219480 |
| Source dataset | uspto-grants-1980_08 |
| ORD ID | ord-e2054230f53e43809c686e6f2bd88ceb |
| Source note | uspto-grants-1980_08 |