Vanadium trichloride oxide → HCID 178514808, compound

HRID 1856444Notes

Reaction equation

HRID 1856444 reaction equation
[O:1]=[V:2].Cl.Cl.Cl.[C:6]1([C:38]2[CH:43]=[CH:42][CH:41]=[CH:40][CH:39]=2)[CH:11]=[CH:10][C:9]([Si:12]([C:26]2[CH:31]=[CH:30][C:29]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)=[CH:28][CH:27]=2)([C:14]2[CH:19]=[CH:18][C:17]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)=[CH:16][CH:15]=2)[OH:13])=[CH:8][CH:7]=1>>[O-2:13].[C:17]1([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:16]=[CH:15][C:14]([Si:12]([C:26]2[CH:31]=[CH:30][C:29]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)=[CH:28][CH:27]=2)([C:9]2[CH:10]=[CH:11][C:6]([C:38]3[CH:39]=[CH:40][CH:41]=[CH:42][CH:43]=3)=[CH:7][CH:8]=2)[O:13][V+2:2]([O:13][Si:12]([C:26]2[CH:31]=[CH:30][C:29]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)=[CH:28][CH:27]=2)([C:9]2[CH:10]=[CH:11][C:6]([C:38]3[CH:39]=[CH:40][CH:41]=[CH:42][CH:43]=3)=[CH:7][CH:8]=2)[C:14]2[CH:15]=[CH:16][C:17]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)=[CH:18][CH:19]=2)[O:1][Si:12]([C:26]2[CH:27]=[CH:28][C:29]([C:32]3[CH:33]=[CH:34][CH:35]=[CH:36][CH:37]=3)=[CH:30][CH:31]=2)([C:14]2[CH:19]=[CH:18][C:17]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)=[CH:16][CH:15]=2)[C:9]2[CH:10]=[CH:11][C:6]([C:38]3[CH:39]=[CH:40][CH:41]=[CH:42][CH:43]=3)=[CH:7][CH:8]=2)=[CH:19][CH:18]=1

Participants

3

Reactant 2

HCID 24410Vanadium trichloride oxideHCID 3521950Tris(4-biphenylyl)silanol

Product 1

HCID 178514808HCID 178514808, compound

Procedure

vanadium oxytrichloride was reacted with tri-4-biphenylyl-silanol (m.p.=199°-200° C.) to produce tris[tri-(4-biphenylyl)-siloxy] vanadium oxide.

Sources & evidence

ORD record
ord-3cb724ff340f4affa89257e959a5a3fc
Source dataset
uspto-grants-1980_08
Patent number
US04219506

Reaction notes

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