HuagongsheHuagongshe Chemistry Print Report · For research reference only
Bromine → HCID 23345398, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Bromine | HCID 24408 | — |
| Reactant | 1,3-Dihydro-2H-2-benzothiophene-2,2-dione | HCID 313675 | — |
| Catalyst | Iron | HCID 23925 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | HCID 23345398 | HCID 23345398 | — |
Reaction Steps
1,3-Dihydrobenzo[c]thiophene 2,2-dioxide [Chem. & Ind., 1024 (1965)] is brominated according to the method described in Khim. Tadzh., 107 (1973), [C.A., 84, 89,930 (1976)], using bromine (1.1 equivalents) in refluxing carbon tetrachloride which contains iron until the bromine color is dissipated. Removal of the carbon tetrachloride and recrystallization from ethanol gives 4-bromo-1,3-dihydrobenzo[c]thiophene 2,2-dioxide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04219648 |
| Source dataset | uspto-grants-1980_08 |
| ORD ID | ord-bbe8f740211946818cbc177c0ededa54 |
| Source note | uspto-grants-1980_08 |