HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl 3-methyl-2-butenoate → HCID 53981980, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl 3-methyl-2-butenoate | HCID 13546 | — |
| Reactant | Lithium | HCID 3028194 | — |
| Reactant | HCID 54297158 | HCID 54297158 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 53981980 | HCID 53981980 | — |
Reaction Steps
To the lithium salt of methylsenecioate in THF at -70° was added an equimolar amount of 1-nitro-2-methyl-1,3-butadiene. Quenching in ice, followed by ether extraction yielded a crude product which was purified by Kugelrohr distillation and chromatography. The product had the appearance of a yellowish colored liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04219660 |
| Source dataset | uspto-grants-1980_08 |
| ORD ID | ord-f35de5ed126e4d53819cf6b3b42d3414 |
| Source note | uspto-grants-1980_08 |