3,5-Dinitrobenzoyl chloride → HCID 86737165, compound

HRID 1856505Notes

Reaction equation

HRID 1856505 reaction equation
[N+:1]([CH2:4][C:5]([CH3:9])=[CH:6][CH2:7][OH:8])([O-:3])=[O:2].[N+:10]([C:13]1[CH:14]=[C:15]([CH:19]=[C:20]([N+:22]([O-:24])=[O:23])[CH:21]=1)[C:16](Cl)=[O:17])([O-:12])=[O:11]>C1C=CC=CC=1>[CH3:9][C:5]([CH2:4][N+:1]([O-:3])=[O:2])=[CH:6][CH2:7][OH:8].[N+:10]([C:13]1[CH:14]=[C:15]([CH:19]=[C:20]([N+:22]([O-:24])=[O:23])[CH:21]=1)[C:16]([O-:2])=[O:17])([O-:12])=[O:11]

Participants

4

Reactant 2

HCID 74323,5-Dinitrobenzoyl chlorideHCID 544391273-Methyl-4-nitrobut-2-en-1-ol

Product 1

HCID 86737165HCID 86737165, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

To 0.1 Mol of 4-nitro-3-methyl-2-butenol in benzene was added 0.1 Mol of 3,5-dinitrobenzoylchloride and stirred overnight. The benzene was evaporated and the residue was stirred in sat. sodiumbicarbonate solution for 1 hour. The solid product was filtered and recrystallized first from alcohol water and then from ethylacetate/hexane. The product was obtained as a yellow crystalline material, m.p. 111°-113°.

Workup

  1. customThe benzene was evaporated
  2. stirringthe residue was stirred in sat. sodiumbicarbonate solution for 1 hour
  3. filtrationThe solid product was filtered
  4. customrecrystallized first from alcohol water
  5. customThe product was obtained as a yellow crystalline material, m.p. 111°-113°

Sources & evidence

ORD record
ord-9e61982c007a4d84baf5ef7eb78d2e60
Source dataset
uspto-grants-1980_08
Patent number
US04219660

Reaction notes

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