Tert-Butylamine → HCID 11142504, compound

Participants

Reaction Steps

To a 500 ml round bottom flask containing 1.98 g (0.0064 mole) of (1H-cyclopenta[l]phenanthrene-2-yl)dimethylchlorosilane and 250 ml of hexane was added 2.00 ml (0.0160 mole) of t-butylamine. The reaction mixture was allowed to stir for several days, then filtered using diatomaceous earth filter aid (Celite™), washed twice with hexane. The product was isolated by removing residual solvent under reduced pressure. The isolated yield was 1.98 g (88.9 percent). 1H NMR analysis indicated the predominant isomer was substituted at the 2 position due to migration of the silane substituent.

Provenance & Evidence