Tert-Butylamine → HCID 22124216, compound

Participants

Reaction Steps

To a 500 ml round bottom flask containing 2.420 g (0.00718 mole) of (1,3-dimethyl-1H-cyclopenta[l]phenanthrene-2-yl)dimethylchlorosilane and 250 ml of methylene chloride was added 1.331 g (0.0180 mole) of t-butylamine. The reaction mixture was allowed to stir for several days, then filtered using diatomaceous earth filter aid (Celite™), washed twice with hexane. The product was isolated by removing residual solvent under reduced pressure. The isolated yield was 2.120 g (79.0 percent). 1H NMR analysis indicated the predominant isomer was substituted at the 2 position.

Provenance & Evidence