2,4-Dimethylpent-2-ene → HCID 22129039, compound

Participants

Reaction Steps

A one-liter autoclave equipped with a stirrer was charged in a nitrogen atmosphere with 55 grams (0.56 mol) of 2,4-dimethyl-3-pentene, 148 grams (1.1 mol) of trichlorosilane and 17 grams (70 mmols) of 1,1'-azobis(cyclohexane-1-carbonitrile) and the mixture was reacted at a temperature of 130° C. for 4 days. The resulting reaction mixture was purified by distillation thereby obtaining 117 grams (0.50 mol) of 2,4-dimethyl-3-trichlorosilylpentane. The structure of the resulting product was identified by 1HNMR.

Provenance & Evidence