Trichlorosilane → HCID 22129028, compound

HRID 1858397Notes

Reaction equation

HRID 1858397 reaction equation
[CH2:1]([C:3](=[CH:6][CH:7]([CH2:10][CH3:11])[CH2:8][CH3:9])[CH2:4][CH3:5])[CH3:2].[Cl:12][SiH:13]([Cl:15])[Cl:14].N(C1(C#N)CCCCC1)=NC1(C#N)CCCCC1>>[CH2:4]([CH:3]([CH:6]([Si:13]([Cl:15])([Cl:14])[Cl:12])[CH:7]([CH2:10][CH3:11])[CH2:8][CH3:9])[CH2:1][CH3:2])[CH3:5]

Participants

4

Reactant 3

HCID 24811TrichlorosilaneHCID 749781,1'-Azobis(cyclohexanecarbonitrile)HCID 22129032HCID 22129032, compound

Product 1

HCID 22129028HCID 22129028, compoundYield 56%

Procedure

A one-liter autoclave equipped with a stirrer was charged in a nitrogen atmosphere with 77 grams (0.50 mol) of 3,5-diethyl-3-heptene, 134 grams (1.0 mol) of trichlorosilane and 24 grams (0.1mol) of 1,1'-azobis(cyclohexane-1-carbonitrile) and the mixture was reacted at a temperature of 130° C. for 5 days. The resulting reaction mixture was purified by distillation thereby obtaining 80 grams (0.28 mol) of 3,5-diethyl-4-trichlorosilylheptane. The structure of the resulting product was identified by 1H-NMR.

Workup

  1. customA one-liter autoclave equipped with a stirrer
  2. customthe mixture was reacted at a temperature of 130° C. for 5 days
  3. customThe resulting reaction mixture
  4. distillationwas purified by distillation

Sources & evidence

ORD record
ord-35e4949ac8494f0694340fa62fa4fc38
Source dataset
uspto-grants-2000_11
Patent number
US06150549

Reaction notes

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