Trichlorosilane → HCID 22129055, compound

HRID 1858398Notes

Reaction equation

HRID 1858398 reaction equation
[CH3:1][C:2](=[CH:5][CH:6]([CH3:9])[CH2:7][CH3:8])[CH2:3][CH3:4].[Cl:10][SiH:11]([Cl:13])[Cl:12].N(C1(C#N)CCCCC1)=NC1(C#N)CCCCC1>>[CH3:1][CH:2]([CH:5]([Si:11]([Cl:13])([Cl:12])[Cl:10])[CH:6]([CH3:9])[CH2:7][CH3:8])[CH2:3][CH3:4]

Participants

4

Reactant 3

HCID 24811TrichlorosilaneHCID 749781,1'-Azobis(cyclohexanecarbonitrile)HCID 5218943,5-Dimethyl-3-heptene

Product 1

HCID 22129055HCID 22129055, compoundYield 58.3%

Procedure

A one-liter autoclave equipped with a stirrer was charged in a nitrogen atmosphere with 76 grams (0.60 mol) of 3,5-dimethyl-3-heptene, 161 grams (1.2 mol) of trichlorosilane and 29 grams (0.12 mol) of 1,1'-azobis(cyclohexane-1-carbonitrile) and the mixture was reacted at a temperature of 130° C. for 5 days. The resulting reaction mixture was purified by distillation thereby obtaining 92 grams (0.35 mol) of 3,5-dimethyl-4-trichlorosilylheptane. The structure of the resulting product was identified by 1H-NMR.

Workup

  1. customA one-liter autoclave equipped with a stirrer
  2. customthe mixture was reacted at a temperature of 130° C. for 5 days
  3. customThe resulting reaction mixture
  4. distillationwas purified by distillation

Sources & evidence

ORD record
ord-fb2578a56e76481c99c99a6ef3efbb03
Source dataset
uspto-grants-2000_11
Patent number
US06150549

Reaction notes

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