Trichlorosilane → HCID 22129165, compound

HRID 1858400Notes

Reaction equation

HRID 1858400 reaction equation
[CH3:1][C:2]1[CH2:6][CH2:5][CH:4]([CH3:7])[CH:3]=1.[Cl:8][SiH:9]([Cl:11])[Cl:10].N(C1(C#N)CCCCC1)=NC1(C#N)CCCCC1>>[CH3:1][CH:2]1[CH2:6][CH2:5][CH:4]([CH3:7])[CH:3]1[Si:9]([Cl:11])([Cl:10])[Cl:8]

Participants

4

Reactant 3

HCID 24811TrichlorosilaneHCID 749781,1'-Azobis(cyclohexanecarbonitrile)HCID 30173201,3-Dimethylcyclopent-1-ene

Product 1

HCID 22129165HCID 22129165, compoundYield 73%

Procedure

A one-liter autoclave equipped with a stirrer was charged in a nitrogen atmosphere with 49 grams (0.51 mol) of 1,3-dimethylcyclopentene, 138 grams (1.0 mol) of trichlorosilane and 24 grams (0.1 mol) of 1,1'-azobis(cyclohexane-1-carbonitrile) and the mixture was reacted at a temperature of 130° C. for 3 days. The resulting reaction mixture was purified by distillation thereby obtaining 85 grams (0.37 mol) of 2,5-dimethylcyclopentyltrichlorosilane. The structure of the resulting product was identified by 1H-NMR analysis.

Workup

  1. customA one-liter autoclave equipped with a stirrer
  2. customthe mixture was reacted at a temperature of 130° C. for 3 days
  3. customThe resulting reaction mixture
  4. distillationwas purified by distillation

Sources & evidence

ORD record
ord-463a85781e4b4151b24b5c07467c6344
Source dataset
uspto-grants-2000_11
Patent number
US06150549

Reaction notes

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