Aluminium lithium hydride → HCID 22126362, compound

HRID 1858794Notes

Reaction equation

HRID 1858794 reaction equation
[CH3:1][O:2][C:3]1[C:12]2[C:7](=[C:8]([O:13][CH3:14])[CH:9]=[CH:10][CH:11]=2)[CH:6]=[C:5]([C:15](OC)=[O:16])[CH:4]=1.[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH3:1][O:2][C:3]1[C:12]2[C:7](=[C:8]([O:13][CH3:14])[CH:9]=[CH:10][CH:11]=2)[CH:6]=[C:5]([CH2:15][OH:16])[CH:4]=1

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 22126413HCID 22126413, compound

Product 1

HCID 22126362HCID 22126362, compound

Procedure

In an analogous manner to that described in Example 5b), by reducing methyl 4,8-dimethoxy-naphthalene-2-carboxylate (J.Chem.Soc. 1959, 1024) by means of lithium aluminium hydride there was obtained (4,8-dimethoxy-naphthalen-2-yl)-methanol, MS: 218 (M)+, as a colourless solid.

Sources & evidence

ORD record
ord-5d917e4782cf476ab854bad96eb5bccb
Source dataset
uspto-grants-2000_11
Patent number
US06150526

Reaction notes

Loading…