Aluminium lithium hydride → HCID 22128826, compound

HRID 1858808Notes

Reaction equation

HRID 1858808 reaction equation
[CH3:1][O:2][CH2:3][CH2:4][O:5][CH2:6][O:7][C:8]1[C:17]2[C:12](=[CH:13][CH:14]=[CH:15][CH:16]=2)[CH:11]=[CH:10][C:9]=1[C:18](OC)=[O:19].[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH3:1][O:2][CH2:3][CH2:4][O:5][CH2:6][O:7][C:8]1[C:17]2[C:12](=[CH:13][CH:14]=[CH:15][CH:16]=2)[CH:11]=[CH:10][C:9]=1[CH2:18][OH:19]

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 22128084HCID 22128084, compound

Product 1

HCID 22128826HCID 22128826, compound

Procedure

In an analogous manner to that described in Example 5(b)-(c), from methyl 1-(2-methoxy-ethoxymethoxy)-naphthalene-2-carboxylate by reduction by means of lithium aluminium hydride there was obtained [1-(2-methoxy-ethoxymethoxy)-naphthalen-2-yl]-methanol, which was then converted into 2-chloromethyl-1-(2-methoxy-ethoxymethoxy)-naphthalene; MS: 280 (M)+.

Sources & evidence

ORD record
ord-04730c9a811d4042aea4acb19de1592b
Source dataset
uspto-grants-2000_11
Patent number
US06150526

Reaction notes

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