Sodium Azide → HCID 18625899, compound

HRID 1859991Notes

Reaction equation

HRID 1859991 reaction equation
CS(O[CH2:6][CH2:7][O:8][C:9]1[CH:14]=[CH:13][C:12]([CH2:15][C:16]([CH3:29])([O:22][C:23]2[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=2)[C:17]([O:19][CH2:20][CH3:21])=[O:18])=[CH:11][CH:10]=1)(=O)=O.[N-:30]=[N+:31]=[N-:32].[Na+]>>[N:30]([CH2:6][CH2:7][O:8][C:9]1[CH:14]=[CH:13][C:12]([CH2:15][C:16]([CH3:29])([O:22][C:23]2[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=2)[C:17]([O:19][CH2:20][CH3:21])=[O:18])=[CH:11][CH:10]=1)=[N+:31]=[N-:32]

Participants

3

Reactant 2

HCID 33557Sodium AzideHCID 18625834HCID 18625834, compound

Product 1

HCID 18625899HCID 18625899, compound

Procedure

In a similar manner to that described in Reference example 3(h), a reaction was carried out using ethyl 3-[4-(2-methanesulfonyloxyethoxy)phenyl]-2-methyl-2-phenoxypropionate (i1.42 g), which is the product of Reference example 8(e), and sodium azide (0.66 g) and the reaction mixture was treated to afford the desired compound (0.82 g) as a syrup.

Workup

  1. additionthe reaction mixture was treated

Sources & evidence

ORD record
ord-810b8df7f21849a6a2d3a035485a08b7
Source dataset
uspto-grants-2003_03
Patent number
US06528525B1

Reaction notes

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