HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → Tert-butyl-(4-oxiranylmethoxy-phenoxy)-diphenylsilane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Cyclohexene | HCID 8079 | — |
| Reactant | 1-Benzyloxy-4-diphenyl(tert-butyl)silyloxybenzene | HCID 532606 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Product | Tert-butyl-(4-oxiranylmethoxy-phenoxy)-diphenylsilane | HCID 12045564 | — |
Reaction Steps
(4-Benzyloxy-phenoxy)-tert-butyl-diphenyl-silane (32.5 g, 67 mmol) was dissolved in ethanol. 10% Palladium on carbon (3.0 g) was added followed by cyclohexene (100 mL). The mixture was heated at reflux for 16 hours. The reaction was cooled to room temperature and filtered through Celite. The solvent was removed in vacuo to yield the title compound (22.0 g, 63 mmol).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06537994B2 |
| Source dataset | uspto-grants-2003_03 |
| ORD ID | ord-97d28f0209dc4541b0b63303345470fe |
| Source note | uspto-grants-2003_03 |