Acetic Acid → 5-Nitroso-2,4,6-pyrimidinetriamine

HRID 1863065Notes

Reaction equation

HRID 1863065 reaction equation
[NH2:1][C:2]1[N:7]=[C:6]([NH2:8])[CH:5]=[C:4]([NH2:9])[N:3]=1.[N:10]([O-])=[O:11].[Na+].CC(O)=O>O>[NH2:1][C:2]1[N:7]=[C:6]([NH2:8])[C:5]([N:10]=[O:11])=[C:4]([NH2:9])[N:3]=1

Participants

5

Reactant 3

HCID 176Acetic AcidHCID 138632,4,6-TriaminopyrimidineHCID 23668193Sodium Nitrite

Product 1

HCID 705045-Nitroso-2,4,6-pyrimidinetriamine

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The process according to claim 1 wherein 2,4,6-triaminopyrimidine is reacted with an equimolar amount of sodium nitrite in the presence of about 1.5 molar amount of HOAc in the presence of water to produce the intermediate 2,4,6-triamino-5-nitrosopyrimidine in the form of a stirrable slurry.

Sources & evidence

ORD record
ord-1077a2e729b54dbda604fe763c35e0c5
Source dataset
uspto-grants-1979_09
Patent number
US04167633

Reaction notes

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