HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl vinyl ketone → HCID 12781344, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl vinyl ketone | HCID 6570 | — |
| Reactant | 6-Nitro-1,3-benzodioxol-5-amine | HCID 602665 | — |
| Product | HCID 12781344 | HCID 12781344 | 63% |
Reaction Steps
4-Amino-1,2-methylenedioxy-5-nitrobenzene was made according to the method of Lott, et al.--J. Amer. Chem. Soc., 70, 3621 (1848). It was subjected to a Skraup reaction with methyl vinyl ketone to provide 5,6-methylenedioxy-4-methyl-8-nitroquinoline. The crude compound was crystallized from acetone to give a 63% yield of pure substance; mp 183°-185°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04167638 |
| Source dataset | uspto-grants-1979_09 |
| ORD ID | ord-191439ce78e84f8e987a3245e31466e5 |
| Source note | uspto-grants-1979_09 |