HCID 12531908, compound → HCID 12531884, compound

HRID 1863283Notes

Reaction equation

HRID 1863283 reaction equation
[O:1]([CH:8]([C:13]1[CH:18]=[CH:17][C:16]([O:19][C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)=[CH:15][CH:14]=1)[C:9]([O:11]C)=[O:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1>[OH-].[K+].CO>[O:1]([CH:8]([C:13]1[CH:18]=[CH:17][C:16]([O:19][C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)=[CH:15][CH:14]=1)[C:9]([OH:11])=[O:10])[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

4

Reactant 1

HCID 12531908HCID 12531908, compound

Product 1

HCID 12531884HCID 12531884, compound

Reagents, catalysts & solvents 2

HCID 887MethanolSolventHCID 14797Potassium HydroxideSolvent

Procedure

A mixture of 3.75 g of methyl α-(phenoxy)-α-[p-(phenoxy)phenyl]acetate in 20 ml of 20% KOH and 5 ml of methanol is refluxed overnight to afford, after acidification, a white solid, mp 144°-146° C. (from chloroform-petroleum ether).

Workup

  1. temperatureis refluxed overnight
  2. customto afford

Sources & evidence

ORD record
ord-b25844d5ac6c4996ba74ed7b387eb703
Source dataset
uspto-grants-1979_09
Patent number
US04168385

Reaction notes

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