p-Chlorothiophenol → HCID 20392573, compound

HRID 1863289Notes

Reaction equation

HRID 1863289 reaction equation
Br[CH:2]([C:7]1[CH:12]=[CH:11][C:10]([I:13])=[CH:9][CH:8]=1)[C:3]([O:5][CH3:6])=[O:4].[Cl:14][C:15]1[CH:20]=[CH:19][C:18]([SH:21])=[CH:17][CH:16]=1>CO>[Cl:14][C:15]1[CH:20]=[CH:19][C:18]([S:21][CH:2]([C:7]2[CH:12]=[CH:11][C:10]([I:13])=[CH:9][CH:8]=2)[C:3]([O:5][CH3:6])=[O:4])=[CH:17][CH:16]=1

Participants

4

Reactant 2

HCID 7815p-ChlorothiophenolHCID 20392584Methyl α-bromo-4-iodobenzeneacetate

Product 1

HCID 20392573HCID 20392573, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

In a similar manner as in Example 29, 12.7 g of methyl α-bromo-α-(p-iodophenyl)acetate is reacted with 6.47 g of 4-chlorothiophenol in methanol to yield a white solid, mp 44°-46° C.

Workup

  1. customto yield a white solid, mp 44°-46° C.

Sources & evidence

ORD record
ord-0e7b3fe228514286b77212d3acd3297c
Source dataset
uspto-grants-1979_09
Patent number
US04168385

Reaction notes

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