Thiophenol → HCID 54318056, compound

HRID 1863290Notes

Reaction equation

HRID 1863290 reaction equation
Br[CH:2]([C:7]1[CH:12]=[CH:11][C:10]([I:13])=[CH:9][CH:8]=1)[C:3]([O:5][CH3:6])=[O:4].[C:14]1([SH:20])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>CO>[C:14]1([S:20][CH:2]([C:7]2[CH:12]=[CH:11][C:10]([I:13])=[CH:9][CH:8]=2)[C:3]([O:5][CH3:6])=[O:4])[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

Participants

4

Reactant 2

HCID 7969ThiophenolHCID 20392584Methyl α-bromo-4-iodobenzeneacetate

Product 1

HCID 54318056HCID 54318056, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

In a similar manner as in Example 29, 14.2 g of methyl α-bromo-α-(p-iodophenyl)acetate is reacted with 5.5 g of thiophenol in methanol to yield white crystals, mp 62.5°-65° C.

Workup

  1. customto yield white crystals, mp 62.5°-65° C.

Sources & evidence

ORD record
ord-56c93ec9dab343ee844b10493ffa7fe0
Source dataset
uspto-grants-1979_09
Patent number
US04168385

Reaction notes

Loading…