HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenol, 3-(1,1-dimethylethyl)- → Methyl alpha-(m-tert-butylphenoxy)-alpha-[p-(p-chlorophenoxy)phenyl]acetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenol, 3-(1,1-dimethylethyl)- | HCID 11450 | — |
| Reactant | Methyl alpha-Bromo-alpha-[p-(p-chlorophenoxy)phenyl]acetate | HCID 20392594 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | Methyl alpha-(m-tert-butylphenoxy)-alpha-[p-(p-chlorophenoxy)phenyl]acetate | HCID 12531847 | — |
Reaction Steps
In an identical manner as in Example 39, 7.11 g of methyl α-bromo-α-[p-(p-chlorophenoxy)phenyl]acetate is reacted with 3.75 g of 3-tert-butylphenol in methanol to give a yellow oil. Fractional bulb-to-bulb distillation gives the product as a viscous yellow oil (182° C. @ 0.05 mm).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04168385 |
| Source dataset | uspto-grants-1979_09 |
| ORD ID | ord-a9d93e6ef25e4d58aff53e0e6ddb5dac |
| Source note | uspto-grants-1979_09 |