Phenol, 3-(1,1-dimethylethyl)- → HCID 12531893, compound

HRID 1863337Notes

Reaction equation

HRID 1863337 reaction equation
Br[CH:2]([C:7]1[CH:12]=[CH:11][C:10]([O:13][C:14]2[CH:19]=[CH:18][C:17]([C:20]([CH3:23])([CH3:22])[CH3:21])=[CH:16][CH:15]=2)=[CH:9][CH:8]=1)[C:3]([O:5][CH3:6])=[O:4].[C:24]([C:28]1[CH:29]=[C:30]([OH:34])[CH:31]=[CH:32][CH:33]=1)([CH3:27])([CH3:26])[CH3:25]>>[C:24]([C:28]1[CH:29]=[C:30]([CH:31]=[CH:32][CH:33]=1)[O:34][CH:2]([C:7]1[CH:12]=[CH:11][C:10]([O:13][C:14]2[CH:19]=[CH:18][C:17]([C:20]([CH3:23])([CH3:22])[CH3:21])=[CH:16][CH:15]=2)=[CH:9][CH:8]=1)[C:3]([O:5][CH3:6])=[O:4])([CH3:27])([CH3:25])[CH3:26]

Participants

3

Reactant 2

HCID 11450Phenol, 3-(1,1-dimethylethyl)-HCID 20392606HCID 20392606, compound

Product 1

HCID 12531893HCID 12531893, compoundYield 82.9%

Procedure

In a manner similar to Example 16, 7.54 g of methyl α-bromo-α-[p-(p-tert-butylphenoxy)phenyl]acetate was treated with 3.75 g of m-tert-butylphenol to yield 7.4 g of product as a pale yellow glass.

Sources & evidence

ORD record
ord-1b14e458cac54f948cfc6762b7ab0dd9
Source dataset
uspto-grants-1979_09
Patent number
US04168385

Reaction notes

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