4-tert-Butylphenol → HCID 12531900, compound

HRID 1863343Notes

Reaction equation

HRID 1863343 reaction equation
Br[CH:2]([C:7]1[CH:12]=[CH:11][C:10]([S:13][C:14]2[CH:19]=[CH:18][C:17]([Cl:20])=[CH:16][CH:15]=2)=[CH:9][CH:8]=1)[C:3]([O:5][CH3:6])=[O:4].[C:21]([C:25]1[CH:30]=[CH:29][C:28]([OH:31])=[CH:27][CH:26]=1)([CH3:24])([CH3:23])[CH3:22]>>[C:21]([C:25]1[CH:26]=[CH:27][C:28]([O:31][CH:2]([C:7]2[CH:12]=[CH:11][C:10]([S:13][C:14]3[CH:19]=[CH:18][C:17]([Cl:20])=[CH:16][CH:15]=3)=[CH:9][CH:8]=2)[C:3]([O:5][CH3:6])=[O:4])=[CH:29][CH:30]=1)([CH3:24])([CH3:22])[CH3:23]

Participants

3

Reactant 2

HCID 73934-tert-ButylphenolHCID 20392605HCID 20392605, compound

Product 1

HCID 12531900HCID 12531900, compoundYield 54.4%

Procedure

In a manner similar to Example 16, 7.43 g of methyl α-bromo-α-[p-(p-chlorophenylthio)phenyl]acetate was reacted with 3.75 g of p-tert-butylphenol. Filtration of the crude reaction mixture yielded 5.4 g of white platelets, which yielded 4.8 g of white crystals, mp 106.5°-108.5° C. on recrystallization from 100 ml of 80:20 hexane:chloroform.

Workup

  1. filtrationFiltration of the crude
  2. customreaction mixture
  3. customyielded 5.4 g of white platelets, which

Sources & evidence

ORD record
ord-3b98f908a9984c628f0f06650e45ca87
Source dataset
uspto-grants-1979_09
Patent number
US04168385

Reaction notes

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