関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Tetramethylammonium hydroxide | HCID 60966 | — |
| 反応物 | Phosphoric acid, bis(1,1-dimethylethyl) ester | HCID 429756 | — |
| 溶媒 | Acetone | HCID 180 | — |
| 生成物 | Tetramethylammonium ditert-butyl hydrogen phosphate | HCID 86609697 | — |
反応手順
A solution of the di-tert-butyl hydrogen phosphate obtained in step a) was dissolved in acetone (10 ml) and cooled to 0° C. To this solution was added a 10% aqueous solution of tetramethylammonium hydroxide (2.4 ml, 2.6 mmol), and the homogeneous solution was evaporated under reduced pressure to provide a solid, which was crystallized from refluxing 1,2-dimethoxyethane to provide tetramethylammonium di-tert-butyl hydrogen phosphate as a white solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07625881B2 |
|---|
| 出典データセット | uspto-grants-2009_12 |
|---|
| ORD ID | ord-7aaed2f3358b42bab3ab6c1a155988f1 |
|---|
| 出典メモ | uspto-grants-2009_12 |
|---|
