HuagongsheHuagongshe Chemistry Print Report · For research reference only
3,3'-Bis(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4'-oxydianiline → 4,4'-Diaminodiphenyl Ether
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3,3'-Bis(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4'-oxydianiline | HCID 86623391 | — |
| Reactant | 3-(1-Hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4'-oxydianiline | HCID 86623392 | — |
| Product | 4,4'-Diaminodiphenyl Ether | HCID 7579 | — |
| Product | Hexafluoroacetone | HCID 12695 | — |
| Product | 3-(1-Hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4'-oxydianiline | HCID 86623392 | — |
Reaction Steps
The reaction liquid was found by gas chromatography (GC) analysis to contain 43.5% of the target compound, 3-(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4′-oxydianiline, 2.9% of 3,3′-bis(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4′-oxydianiline, and 46.6% of the total of various imines produced by the reaction of hexafluoroacetone with the amine moiety of 4,4′-oxydianiline.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07629434B2 |
| Source dataset | uspto-grants-2009_12 |
| ORD ID | ord-2335ce8ca32544439fd7fe3baca89c0c |
| Source note | uspto-grants-2009_12 |