Dichloromethane → Methyl 2-hydroxy-4-[3-oxo-3-(4,4-dimethylthiochroman-6-yl)-1-propynyl]benzoate

HRID 186661Notes

Reaction equation

HRID 186661 reaction equation
[Cl:49][CH2:50][Cl:51].[Cr:28]([O:29][Cr:30]([O-:31])(=[O:32])=[O:33])([O-:34])(=[O:35])=[O:36].[OH:1][c:2]1[c:3]([C:4](=[O:5])[O:6][CH3:7])[cH:8][cH:9][c:10]([C:12]#[C:13][CH:14]([c:15]2[cH:16][c:17]3[c:22]([cH:23][cH:24]2)[S:21][CH2:20][CH2:19][C:18]3([CH3:25])[CH3:26])[OH:27])[cH:11]1.[nH+:37]1[cH:38][cH:39][cH:40][cH:41][cH:42]1.[nH+:43]1[cH:44][cH:45][cH:46][cH:47][cH:48]1>>[OH:1][c:2]1[c:3]([C:4](=[O:5])[O:6][CH3:7])[cH:8][cH:9][c:10]([C:12]#[C:13][C:14]([c:15]2[cH:16][c:17]3[c:22]([cH:23][cH:24]2)[S:21][CH2:20][CH2:19][C:18]3([CH3:25])[CH3:26])=[O:27])[cH:11]1

Participants

5

Reactant 4

HCID 6344DichloromethaneHCID 24503Dichromate ionHCID 4989215Pyridinium2×HCID 22619455Methyl 2-hydroxy-4-[3-hydroxy-3-(4,4-dimethylthiochroman-6-yl)-1-propynyl]benzoate

Product 1

HCID 22619445Methyl 2-hydroxy-4-[3-oxo-3-(4,4-dimethylthiochroman-6-yl)-1-propynyl]benzoate

Sources & evidence

ORD record
ord-7cbb60043ef3411f814bb598ccc95823
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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