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HRID1867481

反应详情

EQUATION

反应方程式

HRID 1867481 的结构方程式

REACTANTS

反应物

2
结构：CCC[CH2][Sn]([C]#C[Si](C)(C)C)([CH2]CCC)[CH2]CCC
HCID639663

Trimethyl[(tributylstannyl)ethynyl]silane

C17H36SiSn

结构：Oc1ccc(-c2cc(Br)c3cc(O)ccc3n2)cc1
HCID135454802

未命名化合物

PRODUCTS

生成物

1
结构：C[Si](C)(C)C#Cc1cc(-c2ccc(O)cc2)nc2ccc(O)cc12
HCID135409783

未命名化合物

收率 83%

PROCEDURE

实验过程

This compound was prepared from 6a and (trimethylsilylethynyl)tributyltin according to method J. Yellow powder; Yield: 83%; mp 210° C. (dec.); 1H-NMR (300 MHz, acetone-d6) δ 0.38 (s, 9H), 7.02 (d, J=8.7 Hz, 2H), 7.44 (dd, J=9.1, 2.7 Hz, 1H), 7.63 (d, J=2.7 Hz, 1H), 7.99 (d, J=9.1 Hz, 1H), 8.05 (s, 1H), 8.18 (d, J=8.7 Hz, 2H), 8.70 (s, 1H), 9.15 (s, 1H); MS (ESI) m/z 332 ([M−H]−), 334 ([M+H]+); Anal. Calcd for C20H19NO2Si: C, 72.04; H, 5.74; N, 4.20. Found: C, 71.67; H, 5.79; N, 4.07.