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HRID1867482

反应详情

EQUATION

反应方程式

HRID 1867482 的结构方程式

REACTANTS

反应物

2
结构：CCC[CH2][Sn]([C]#C[Si](C)(C)C)([CH2]CCC)[CH2]CCC
HCID639663

Trimethyl[(tributylstannyl)ethynyl]silane

C17H36SiSn

结构：Oc1ccc2nc(-c3ccc(O)c(F)c3)cc(Br)c2c1
HCID135477943

未命名化合物

PRODUCTS

生成物

1
结构：C[Si](C)(C)C#Cc1cc(-c2ccc(O)c(F)c2)nc2ccc(O)cc12
HCID135508430

未命名化合物

收率 94%

PROCEDURE

实验过程

This compound was prepared from 6b and (trimethylsilylethynyl)tributyltin according to method J. Red powder; Yield: 94%; 1H-NMR (300 MHz, acetone-d6) δ 0.43 (s, 9H), 7.21 (dd, J=8.8, 8.8 Hz, 1H), 7.51 (dd, J=9.1, 2.7 Hz, 1H), 7.68 (d, J=2.7 Hz, 1H), 8.05 (m, 1H), 8.07 (d, J=9.0 Hz, 1H), 8.13 (s, 1H), 8.18 (dd, J=12.8, 2.1 Hz, 1H), 9.05 (s, 1H), 9.26 (s, 1H); MS (ESI) m/z 350 ([M−H]−), 352 ([M+H]+).