HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1869149Generated: October 30, 2026
Hydrochloric Acid → 4-[2,6-Dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-1-(4-fluoro-phenyl)-butan-1-one
https://huagongshe.com/reaction/1869149
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | 2-{3-[2,6-Dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propyl}-2-(4-fluoro-phenyl)-[1,3]dioxolane | HCID 86613087 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 4-[2,6-Dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-1-(4-fluoro-phenyl)-butan-1-one | HCID 86613088 | — |
Reaction Steps
2.0 g of 2-{3-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-propyl}-2-(4-fluoro-phenyl)-[1,3]dioxolane are dissolved in 20 ml of ethanol, and 1.95 g of 10% aqueous hydrochloric acid are added thereto. After stirring for 16 hours at 80° C., the reaction mixture is concentrated. After purification over silica gel, 4-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-phenoxy]-1-(4-fluoro-phenyl)-butan-1-one is obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US07638514B2 |
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| Source dataset | uspto-grants-2009_12 |
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| ORD ID | ord-3d9577a3b4404f0b81bfbeadf0d92617 |
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| Source note | uspto-grants-2009_12 |
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