Cyclohexylamine → HCID 18695157, compound

HRID 1870083Notes

Reaction equation

HRID 1870083 reaction equation
[CH:1]1([SiH2:10][CH:11]2[C:19]3[C:14](=[CH:15][CH:16]=[CH:17][CH:18]=3)[CH:13]=[CH:12]2)[C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[CH:3]=[CH:2]1.[CH:20]1([NH2:26])[CH2:25][CH2:24][CH2:23][CH2:22][CH2:21]1>C(OCC)C>[CH:20]1([NH:26][Si:10]([NH:26][CH:20]2[CH2:25][CH2:24][CH2:23][CH2:22][CH2:21]2)([CH:11]2[C:19]3[C:14](=[CH:15][CH:16]=[CH:17][CH:18]=3)[CH:13]=[CH:12]2)[CH:1]2[C:9]3[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=3)[CH:3]=[CH:2]2)[CH2:25][CH2:24][CH2:23][CH2:22][CH2:21]1

Participants

4

Reactant 2

HCID 7965CyclohexylamineHCID 131721220HCID 131721220, compound

Product 1

HCID 18695157HCID 18695157, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Conditions

Temperature
0 °C

Procedure

Dichloro, diindenyl silane (6.45 g) was slurried in 20 mL hexanes and 10 mL diethyl ether. The mixture was cooled to 0° C. and 9.2 mL of cyclohexylamine in 10 mL hexanes was added slowly. The mixture was heated to reflux for 1 h, cooled and filtered. The solvent was removed to give di(cyclohexylamino)diindenyl silane as a tan solid (7.60 g).

Workup

  1. temperatureThe mixture was heated
  2. temperatureto reflux for 1 h
  3. temperaturecooled
  4. filtrationfiltered
  5. customThe solvent was removed

Sources & evidence

ORD record
ord-46ba95e6234449b4b448c63e3959691f
Source dataset
uspto-grants-2000_08
Patent number
US06096677

Reaction notes

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