(4-Hydrazinylphenyl)acetic acid → HCID 86755614, compound
Reaction equation
[NH:1]([C:3]1[CH:8]=[CH:7][C:6]([CH2:9][C:10]([OH:12])=[O:11])=[CH:5][CH:4]=1)[NH2:2].[CH3:13][O:14][C:15]1[CH:16]=[C:17]([C:23]2[C@H:32]3[C@H:27]([CH2:28][CH2:29][CH2:30][CH2:31]3)[C:26](=[O:33])N(CCO)N=2)[CH:18]=[CH:19][C:20]=1[O:21][CH3:22]>>[CH3:13][O:14][C:15]1[CH:16]=[C:17]([C:23]2[C@H:32]3[C@H:27]([CH2:28][CH:29]=[CH:30][CH2:31]3)[C:26](=[O:33])[N:1]([C:3]3[CH:4]=[CH:5][C:6]([CH2:9][C:10]([OH:12])=[O:11])=[CH:7][CH:8]=3)[N:2]=2)[CH:18]=[CH:19][C:20]=1[O:21][CH3:22]Participants
3
Procedure
Prepared from compound C and 4-hydrazinophenylacetic acid as described for compound 35. Crystallized from diethyl ether. M.p. 162° C.
Workup
- customCrystallized from diethyl ether
Sources & evidence
- ORD record
- ord-d1295f54c39d4e51a673c3ab87c11363
- Source dataset
- uspto-grants-2000_08
- Patent number
- US06103718
Reaction notes
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