HRID1871581

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：O=C(CO)[C@@H](O)[C@H](O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O)[C@H](O)CO

HCID87177

4-O-Hexopyranosylhex-2-ulose

C12H22O11

2 次

结构：O=C(CO[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O)[C@@H](O)[C@H](O)[C@H](O)CO

HCID162104

Trehalulose

C12H22O11

2 次

结构：O=C(CO)[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O

HCID165577

5-O-Hexopyranosylhex-2-ulose

C12H22O11

结构：OC[C@H]1O[C@H](OC[C@H]2OC(O)(CO)[C@@H](O)[C@@H]2O)[C@H](O)[C@@H](O)[C@@H]1O

HCID439559

6-O-alpha-D-Glucopyranosyl-D-fructofuranose

C12H22O11

结构：O.OC[C@H]1O[C@@H](O[C@@H]2[C@@H](CO)O[C@](O)(CO)[C@H]2O)[C@H](O)[C@@H](O)[C@H]1O

HCID66964417

未命名化合物

2 次

PRODUCTS

生成物

结构：OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO

HCID6251

未命名化合物

PROCEDURE

实验过程

In another preferred embodiment, isomaltulose is hydrogenated. The composition of the reaction product here has a different composition than is expected from a conventional process, where about 50 wt.-% 1,1-GPM and 50 wt.-% 1,6-GPS are generated. The reaction product has a larger 1,1-GPM fraction and a smaller 1,6-GPS fraction. Advantageously, the process of the invention can also be used for hydrogenating trehalulose to 1,1-GPM and 1-0-α-D-glocupyranosil-D-sorbite (1,1-GPS), lactulose to lactite and 3-0-β-D-glucopyranosil-D-mannite, maltulose to 3-0-α-D-glucopyranosil-D-mannite and 4-0-α-D-glucopyranosil-D-sorbite (maltite), and leucrose to 5-0-α-D-glucopyranosil-D-sorbite (1,5-GPS) and 2-0-α-D-glocupyranosil-D-mannite (1,2-GPM). Advantageously, the product has a relatively higher 1,1-GPM fraction in the case of trehalulose, a relatively higher 3-0-α-D-glucopyranosil-D-mannite fraction in the case of maltulose, and a relatively higher 3-0-β-D-glucopyranosil-D-mannite fraction in the case of lactulose. When the aforedescribed glucopyranosil-substituted ketoses are hydrogenated, the invention thus produces an larger mannite epimer fraction and a smaller sorbite epimer fraction in the product.