m-Chloroperbenzoic acid → HCID 18546536, compound

Participants

Reaction Steps

Compound 4,8-dithianonyl acrylate (21) (4.86 g, 20.7 mmol), and mCPBA (9.34 g, 41.4 mmol) were reacted as described in Example 18. The crude product was obtained as a clear oil that was purified by column chromatography (silica gel, 20 wt % acetone/ether, 50 wt % acetone/ether, acetone) to furnish a colorless oil that solidified upon standing in the refrigerator (3.4 g, 27 wt % over three steps from 5) to give compound 24, methyl 3-(acryloyloxy) propyl sulfide.

Provenance & Evidence