Bromine → HCID 15481256, compound

HRID 1873135Notes

Reaction equation

[C:1]([O:4][C:5]1[CH:10]=[C:9]([C:11]2[C:20]3[C:21]4[CH:27]=[CH:26][CH:25]=[CH:24][C:22]=4[S:23][C:19]=3[CH:18]=[C:17]3[C:12]=2[CH:13]=[CH:14][CH:15]=[CH:16]3)[CH:8]=[CH:7][C:6]=1[O:28][C:29](=[O:31])[CH3:30])(=[O:3])[CH3:2].[Br:32]Br>>[C:1]([O:4][C:5]1[CH:10]=[C:9]([C:11]2[C:20]3[C:21]4[CH:27]=[CH:26][CH:25]=[CH:24][C:22]=4[S:23][C:19]=3[C:18]([Br:32])=[C:17]3[C:12]=2[CH:13]=[CH:14][CH:15]=[CH:16]3)[CH:8]=[CH:7][C:6]=1[O:28][C:29](=[O:31])[CH3:30])(=[O:3])[CH3:2]

Participants

Reactant 2

HCID 24408Bromine

HCID 15481253HCID 15481253, compound

Product 1

HCID 15481256HCID 15481256, compound

Procedure

Prepared from acetic acid 2-acetoxy-4-(benzo[b]naphtho[2,3-d]thiophen-11-yl)-phenyl ester (Example 36) according to the procedure of Example 37. White solid: mp 178-179° C.: MS (EI): [M+], 1 bromine isotope pattern, 504, 506; Anal. Calc. for C26H17BrO4S: C, 61.79, H, 3.39, N, 0.00. Found: C, 61.37, H, 3.32, N, 0.11.

Sources & evidence

ORD record: ord-6282bcea4e134a849427110b1ae4b3c0
Source dataset: uspto-grants-2000_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06110962

Reaction notes

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