Bromine → HCID 15481260, compound

HRID 1873137Notes

Reaction equation

HRID 1873137 reaction equation
C([O:4][C:5]1[CH:10]=[C:9]([C:11]2[C:20]3[C:21]4[CH:27]=[CH:26][CH:25]=[CH:24][C:22]=4[S:23][C:19]=3[C:18]([Br:28])=[C:17]3[C:12]=2[CH:13]=[CH:14][CH:15]=[CH:16]3)[CH:8]=[CH:7][C:6]=1[O:29]C(=O)C)(=O)C.BrBr>>[Br:28][C:18]1[C:19]2[S:23][C:22]3[CH:24]=[CH:25][CH:26]=[CH:27][C:21]=3[C:20]=2[C:11]([C:9]2[CH:10]=[C:5]([OH:4])[C:6]([OH:29])=[CH:7][CH:8]=2)=[C:12]2[C:17]=1[CH:16]=[CH:15][CH:14]=[CH:13]2

Participants

3

Reactant 2

HCID 24408BromineHCID 15481256HCID 15481256, compound

Product 1

HCID 15481260HCID 15481260, compound

Procedure

Prepared from acetic acid 2-acetoxy-4-(6-bromo-benzo[b]naphtho[2,3-d]thiophen-11-yl)-phenyl ester (Example 39) according to the procedure for Example 41. White solid: mp 181-182° C.: MS (EI): [M+], 1 bromine isotope pattern, 420 (95%); Anal. Calc. for C22H13BrO2S: C, 62.72, H, 3.11, N, 0.00. Found: C, 62.11, H, 3.10, N, 0.13.

Sources & evidence

ORD record
ord-c78f3804241041719c236a3b60317d49
Source dataset
uspto-grants-2000_08
Patent number
US06110962

Reaction notes

Loading…