Bromine → HCID 18687808, compound

HRID 1873146Notes

Reaction equation

HRID 1873146 reaction equation
[Br:1][C:2]1[C:14]2[S:13][C:12]3[CH:15]=[CH:16][CH:17]=[CH:18][C:11]=3[C:10]=2[C:9]([C:19]2[CH:20]=[C:21]([OH:26])[C:22]([OH:25])=[CH:23][CH:24]=2)=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[CH:7]2.[Br:27]Br>>[Br:27][C:23]1[CH:24]=[C:19]([C:9]2[C:10]3[C:11]4[CH:18]=[CH:17][CH:16]=[CH:15][C:12]=4[S:13][C:14]=3[C:2]([Br:1])=[C:3]3[C:8]=2[CH:7]=[CH:6][CH:5]=[CH:4]3)[CH:20]=[C:21]([OH:26])[C:22]=1[OH:25]

Participants

3

Reactant 2

HCID 24408BromineHCID 15481260HCID 15481260, compound

Product 1

HCID 18687808HCID 18687808, compound

Procedure

Prepared from 4-(6-bromo-benzo[b]naphtho[2,3-d]thiophen-11-yl)-benzene-1, 2-diol (Example 43) according to the procedure of Example 58. White solid: mp 212-213° C.: MS (EI): [M+], 2 bromine isotope pattern, 498, 500, 502; Anal. Calc. for C22H12Br2O2S:C, 52.83, H, 2.42, N, 0.00. Found: C, 52.08, H, 2.55, N, 0.01.

Sources & evidence

ORD record
ord-7bbb4e976ca047d5af4f2e565d2a5cf6
Source dataset
uspto-grants-2000_08
Patent number
US06110962

Reaction notes

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