Bromine → HCID 18687848, compound

HRID 1873147Notes

Reaction equation

HRID 1873147 reaction equation
[Br:1][C:2]1[C:14]2[S:13][C:12]3[CH:15]=[CH:16][CH:17]=[CH:18][C:11]=3[C:10]=2[C:9]([C:19]2[CH:20]=[C:21]([OH:26])[C:22]([OH:25])=[CH:23][CH:24]=2)=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[CH:7]2.[Br:27]Br>>[Br:27][C:24]1[CH:23]=[C:22]([OH:25])[C:21]([OH:26])=[CH:20][C:19]=1[C:9]1[C:10]2[C:11]3[CH:18]=[CH:17][CH:16]=[CH:15][C:12]=3[S:13][C:14]=2[C:2]([Br:1])=[C:3]2[C:8]=1[CH:7]=[CH:6][CH:5]=[CH:4]2

Participants

3

Reactant 2

HCID 24408BromineHCID 15481260HCID 15481260, compound

Product 1

HCID 18687848HCID 18687848, compound

Procedure

Prepared from 4-(6-bromo-benzo[b]naphtho[2,3-d]thiophen-11-yl)-benzene-1, 2-diol (Example 43) according to the procedure of Example 58. White solid: mp 138-140° C.: MS (EI): [M+], 2 bromine isotope pattern, 498, 500, 502; Anal. Calc. for C22H12Br2O2S: C, 52.83, H, 2.42, N, 0.00. Found: C, 52.17, H, 2.71, N, 0.05.

Sources & evidence

ORD record
ord-e60ca03a18e34eac9bc9c842964d78c6
Source dataset
uspto-grants-2000_08
Patent number
US06110962

Reaction notes

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