HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3-Cyclohexadiene → 5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3-Cyclohexadiene | HCID 11605 | — |
| Reactant | trans-1,2-Bis(phenylsulfonyl)ethylene | HCID 5367099 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 5,6-Di(benzenesulfonyl)bicyclo[2.2.2]oct-2-ene | HCID 12778411 | 96.5% |
Reaction Steps
29.33 g of trans-1,2-diphenylsulfonylethylene was dissolved in 200 ml of toluene, and then, 11.4 ml of 1,3-cyclohexadiene was added, followed by dry distillation for 21 hours and then by recrystallization to obtain 35.66 g (yield: 96.5%) of 5,6-diphenylsulfonyl-bicyclo-[2,2,2]oct-2-ene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08304283B2 |
| Source dataset | uspto-grants-2012_11 |
| ORD ID | ord-7868c6196cd24bbea337434dfb215a42 |
| Source note | uspto-grants-2012_11 |