HCID 59440844, compound → HCID 68483116, compound

HRID 1873457Notes

Reaction equation

HRID 1873457 reaction equation
[CH3:1][CH:2]1[CH:7]=[C:6]([CH3:8])[CH2:5][CH2:4][C:3]1([C:11]([CH3:13])=[CH2:12])[CH:9]=[O:10].[CH2:14]([Mg]Cl)[CH:15]=[CH2:16]>>[CH3:1][CH:2]1[CH:7]=[C:6]([CH3:8])[CH2:5][CH2:4][C:3]1([CH:9]([OH:10])[CH2:16][CH:15]=[CH2:14])[C:11]([CH3:13])=[CH2:12]

Participants

3

Reactant 2

HCID 59440844HCID 59440844, compoundHCID 178418473HCID 178418473, compound

Product 1

HCID 68483116HCID 68483116, compound

Procedure

In analogy to Example 3,1-(2,4-dimethyl-1-(prop-1-en-2-yl)cyclohex-3-enyl)but-3-en-1-ol (91% yield) was prepared starting from 2,4-dimethyl-1-(prop-1-en-2-yl)cyclohex-3-enecarbaldehyde and allylmagnesium chloride

Sources & evidence

ORD record
ord-daab3dfc958e45ec878c2d8eab7081f1
Source dataset
uspto-grants-2012_11
Patent number
US08304380B2

Reaction notes

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