HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → N'-(propan-2-ylidene)(tert-butoxy)carbohydrazide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Acetone | HCID 180 | — |
| Reactant | Sulfuric acid magnesium salt (1:1) | HCID 24083 | — |
| Reactant | tert-Butyl carbazate | HCID 70091 | — |
| Product | N'-(propan-2-ylidene)(tert-butoxy)carbohydrazide | HCID 11435207 | — |
Reaction Steps
To a solution of tert-butylcarbazate (50.0 g, 378 mmol) in 40 mL acetone is added 10 g MgSO4 and 5 mL acetic acid and the reaction mixture is stirred at reflux temperature for 1 h. The reaction mixture is filtered and concentrated in vacuo. The residue is crystallized from diethyl ether/cyclohexane. Yield: 49.4 g.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08304556B2 |
| Source dataset | uspto-grants-2012_11 |
| ORD ID | ord-d1f8b1a159b94a7cb8934a8881dbae1b |
| Source note | uspto-grants-2012_11 |