Aluminium lithium hydride → HCID 57423978, compound

HRID 1875341Notes

Reaction equation

HRID 1875341 reaction equation
[CH3:1][O:2][CH:3]1[CH2:9][N:8]([C:10](OCC)=O)[CH2:7][CH2:6][C:5]2[S:15][CH:16]=[CH:17][C:4]1=2.[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH3:1][O:2][CH:3]1[CH2:9][N:8]([CH3:10])[CH2:7][CH2:6][C:5]2[S:15][CH:16]=[CH:17][C:4]1=2

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 59302562HCID 59302562, compound

Product 1

HCID 57423978HCID 57423978, compound

Procedure

Prepared analogously to Example 60a from ethyl 4-methoxy-4,5,7,8-tetrahydro-thieno[2,3-d]azepin-6-carboxylate (US 2006/0003990) by reduction with lithium aluminum hydride.

Sources & evidence

ORD record
ord-86d91e4db1e04206a5ff466e815fec6c
Source dataset
uspto-grants-2012_11
Patent number
US08309542B2

Reaction notes

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