Nitric Acid → HCID 67094363, compound

HRID 1881201Notes

Reaction equation

HRID 1881201 reaction equation
[OH:1][C:2]1[C:12]([O:13][C:14](=[O:16])[CH3:15])=[CH:11][C:5]2[C:6](=[O:10])[N:7]([CH3:9])[S:8][C:4]=2[CH:3]=1.[N+:17]([O-])([OH:19])=[O:18]>C(O)(=O)C>[OH:1][C:2]1[C:12]([O:13][C:14](=[O:16])[CH3:15])=[CH:11][C:5]2[C:6](=[O:10])[N:7]([CH3:9])[S:8][C:4]=2[C:3]=1[N+:17]([O-:19])=[O:18]

Participants

4

Reactant 2

HCID 944Nitric AcidHCID 67094202HCID 67094202, compound

Product 1

HCID 67094363HCID 67094363, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

To a solution of acetic acid 6-hydroxy-2-methyl-3-oxo-2,3-dihydro-benzo[d]isothiazol-5-yl ester (0.055 g) in acetic acid at 10° C. nitric acid (100% 0.015 g) was added and stirring was continued at room temperature for 15 minutes. The mixture was poured into ice water and extracted with ethyl acetate. Ethyl acetate was dried and evaporated to dryness.

Workup

  1. extractionextracted with ethyl acetate
  2. dry with materialEthyl acetate was dried
  3. customevaporated to dryness

Sources & evidence

ORD record
ord-87e78ab24de8466ab3f50cc53720a650
Source dataset
uspto-grants-2012_11
Patent number
US08318785B2

Reaction notes

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