HRID1881779

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID2734749

Piperonyloyl chloride

C8H5ClO3

HCID11600782

Methyl D-leucinate hydrochloride

C7H16ClNO2

PRODUCTS

生成物

结构：COC(=O)[C@@H](CC(C)C)NC(=O)c1ccc2c(c1)OCO2

HCID797901

未命名化合物

收率 83%

PROCEDURE

实验过程

Prepared in a similar manner to example 1 using benzo[d][1,3]dioxole-5-carbonyl chloride and D-leucine methyl ester hydrochloride. Yield: 83%. 1H NMR (500 MHz, CDCl3): δ 0.98 (m, 6H); 1.63-1.67 (m, 1H); 1.71-1.76 (m, 2H); 3.76 (s, 3H); 4.83 (m, 1H); 6.03 (s, 2H); 6.38 (d, 1H); 6.83 (d, 1H); 7.32 (s, 1H); 7.33 (d, 1H). MS (M+H, 294). m.p: 89-90° C.