HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1884214Generated: October 27, 2026
Sodium Carbonate → Methyl 4-[4-(4-pentoxyphenyl)phenyl]benzoate
https://huagongshe.com/reaction/1884214
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Sodium Carbonate | HCID 10340 | — |
| Reactant | Methyl 4'-iodo-[1,1'-biphenyl]-4-carboxylate | HCID 1394054 | — |
| Reactant | 4-Pentyloxyphenylboronic Acid (contains varying amounts of Anhydride) | HCID 4684888 | — |
| Catalyst | HCID 178418476 | HCID 178418476 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | Methyl 4-[4-(4-pentoxyphenyl)phenyl]benzoate | HCID 9799723 | — |
Reaction Steps
33.8 g (0.1 mol) of methyl 4′-iodobiphenyl-4-carboxylate are introduced together with 29.3 g (0.125 mol) of glycol ester of 4-n-pentoxyphenylboronic acid, 70 mg of bis(triphenylphosphine)palladium dichloride and 15.9 g (0.15 mol) of sodium carbonate into 300 ml of DMF and stirred at 80° C. for 12 hours. After filtration and washing with water, the dried residue is recrystallized from DMF. This affords 20.5 g (45%) of methyl 4″-n-pentoxy-[1,1′:4′,1″]-terphenyl-4-carboxylate of melting point 248° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06762315B1 |
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| Source dataset | uspto-grants-2004_07 |
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| ORD ID | ord-ce48e19a42ff472baded19bebc663d84 |
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| Source note | uspto-grants-2004_07 |
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